Elasticità della gomma e volume escluso intramolecolare
The theory of rubber elasticity is reformulated on the basis of a statistical distribution of the end-to-end distance partially accounting for intramolecular ecluded volume. The relationship between the uniaxial stress, , and the elongation ratio, , is: where is the number of effective chains per unit volume, and is a function with a maximum close to . The elastic modulus for turns out to be 1.27 times the value calculated by the classical Gaussian theory.