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Let $G$ be a finite group and $p$ a prime number. We prove that if $G$ is a finite group of order $\left|\mathrm{PSL}\right(2,p^2\left)\right|$ such that $G$ has an irreducible character of degree $p^2$ and we know that $G$ has no irreducible character $\theta$ such that $2p\mid \theta \left(1\right)$, then $G$ is isomorphic to $\mathrm{PSL}(2,p^2)$. As a consequence of our result we prove that $\mathrm{PSL}(2,p^2)$ is uniquely determined by the structure of its complex group algebra.