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Let $𝒜$ be a noncommutative prime ring equipped with an involution ‘$*$’, and let ${𝒬}_{ms}\left(𝒜\right)$ be the maximal symmetric ring of quotients of $𝒜$. Consider the additive maps $\mathscr{H}$ and $𝒯:𝒜\to {𝒬}_{ms}\left(𝒜\right)$. We prove the following under some inevitable torsion restrictions. (a) If $m$ and $n$ are fixed positive integers such that $(m+n)𝒯\left(a^2\right)=m𝒯\left(a\right)a^{*}+na𝒯\left(a\right)$ for all $a\in 𝒜$ and $(m+n)\mathscr{H}\left(a^2\right)=m\mathscr{H}\left(a\right)a^{*}+na𝒯\left(a\right)$ for all $a\in 𝒜$, then $\mathscr{H}=0$. (b) If $𝒯\left(aba\right)=a𝒯\left(b\right)a^{*}$ for all $a,b\in 𝒜$, then $𝒯=0$. Furthermore, we characterize Jordan left $\tau$-centralizers in semiprime rings admitting an anti-automorphism $\tau$. As applications, we find the structure of...