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We study the duality theory of the weighted multi-parameter Triebel-Lizorkin spaces ${\dot{F}}_p^{\alpha ,q}(\omega ;{ℝ}^{n_1}\times {ℝ}^{n_2})$. This space has been introduced and the result $${\left({\dot{F}}_p^{\alpha ,q}(\omega ;{ℝ}^{n_1}\times {ℝ}^{n_2})\right)}^{*}={\mathrm{CMO}}_p^{-\alpha ,q^{\text{'}}}(\omega ;{ℝ}^{n_1}\times {ℝ}^{n_2})$$ for $0<p\le 1$ has been proved in Ding, Zhu (2017). In this paper, for $1<p<\infty$, $0<q<\infty$ we establish its dual space ${\dot{H}}_p^{\alpha ,q}(\omega ;{ℝ}^{n_1}\times {ℝ}^{n_2})$.

Applying discrete Calderón’s identity, we study weighted multi-parameter mixed Hardy space $H_{\mathrm{mix}}^p(\omega ,{ℝ}^{n_1}\times {ℝ}^{n_2})$. Different from classical multi-parameter Hardy space, this space has characteristics of local Hardy space and Hardy space in different directions, respectively. As applications, we discuss the boundedness on $H_{\mathrm{mix}}^p(\omega ,{ℝ}^{n_1}\times {ℝ}^{n_2})$ of operators in mixed Journé’s class.