On thermodynamics of a gas with vibrating molecules
Ingo Müller (1974)
Annales de l'I.H.P. Physique théorique
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Ingo Müller (1974)
Annales de l'I.H.P. Physique théorique
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W. Muschik, H. Ehrentraut (1996)
Extracta Mathematicae
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J. M. Cardona, S. Forest, R. Sievert (1999)
Extracta Mathematicae
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Baek, S., Srinivasa, A.R. (2003)
Mathematical Problems in Engineering
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Philippe Helluy, Nicolas Seguin (2006)
ESAIM: Mathematical Modelling and Numerical Analysis
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In this work, we propose a general framework for the construction of pressure law for phase transition. These equations of state are particularly suitable for a use in a relaxation finite volume scheme. The approach is based on a constrained convex optimization problem on the mixture entropy. It is valid for both miscible and immiscible mixtures. We also propose a rough pressure law for modelling a super-critical fluid.