A cluster ensemble is a pair $(𝒳,𝒜)$ of positive spaces (i.e. varieties equipped with positive atlases), coming with an action of a symmetry group $\Gamma$. The space $𝒜$ is closely related to the spectrum of a cluster algebra [12]. The two spaces are related by a morphism $p:𝒜\to 𝒳$. The space $𝒜$ is equipped with a closed $2$-form, possibly degenerate, and the space $𝒳$ has a Poisson structure. The map $p$ is compatible with these structures. The dilogarithm together with its motivic and quantum avatars plays a central role...