We determine the duals of the homogeneous matrix-weighted Besov spaces ${Ḃ}_p^{\alpha q}\left(W\right)$ and ${ḃ}_p^{\alpha q}\left(W\right)$ which were previously defined in [5]. If W is a matrix $A_p$ weight, then the dual of ${Ḃ}_p^{\alpha q}\left(W\right)$ can be identified with ${Ḃ}_{p^{\text{'}}}^{-\alpha q^{\text{'}}}\left(W^{-p^{\text{'}}/p}\right)$ and, similarly, $\left[{ḃ}_p^{\alpha q}\left(W\right)\right]*\approx {ḃ}_{p^{\text{'}}}^{-\alpha q^{\text{'}}}\left(W^{-p^{\text{'}}/p}\right)$. Moreover, for certain W which may not be in the $A_p$ class, the duals of ${Ḃ}_p^{\alpha q}\left(W\right)$ and ${ḃ}_p^{\alpha q}\left(W\right)$ are determined and expressed in terms of the Besov spaces ${Ḃ}_{p^{\text{'}}}^{-\alpha q^{\text{'}}}\left(A_Q^{-1}\right)$ and ${ḃ}_{p^{\text{'}}}^{-\alpha q^{\text{'}}}\left(A_Q^{-1}\right)$, which we define in terms of reducing operators ${A_Q}_Q$ associated with W. We also develop the basic theory of these reducing operator Besov spaces. Similar...