Lakshmibai, Mehta and Parameswaran (LMP) introduced the notion of maximal multiplicity vanishing in Frobenius splitting. In this paper we define the algebraic analogue of this concept and construct a Frobenius splitting vanishing with maximal multiplicity on the diagonal of the full flag variety. Our splitting induces a diagonal Frobenius splitting of maximal multiplicity for a special class of smooth Schubert varieties first considered by Kempf. Consequences are Frobenius splitting of tangent bundles,...