Starting from the Grad 13-moment equations for a bimolecular chemical reaction, Navier-Stokes-type equations are derived by asymptotic procedure in the limit of small mean paths. Two physical situations of slow and fast reactions, with their different hydrodynamic variables and conservation equations, are considered separately, yielding different limiting results.

We present in this paper the formal passage from a kinetic model to the incompressible Navier−Stokes equations for a mixture of monoatomic gases with different masses. The starting point of this derivation is the collection of coupled Boltzmann equations for the mixture of gases. The diffusion coefficients for the concentrations of the species, as well as the ones appearing in the equations for velocity and temperature, are explicitly computed under the Maxwell molecule assumption in terms of the...

A linear Boltzmann equation is interpreted as the forward equation for the probability density of a Markov process $\left(K\right(t),i(t),Y(t\left)\right)$ on $({𝕋}^2\times \{1,2\}\times {ℝ}^2)$, where ${𝕋}^2$ is the two-dimensional torus. Here $\left(K\right(t),i(t\left)\right)$ is an autonomous reversible jump process, with waiting times between two jumps with finite expectation value but infinite variance. $Y\left(t\right)$ is an additive functional of $K$, defined as ${\int }_0^{t}v\left(K\left(s\right)\right)\mathrm{d}s$, where $\left|v\right|\sim 1$ for small $k$. We prove that the rescaled process ${(NlnN)}^{-1/2}Y\left(Nt\right)$ converges in distribution to a two-dimensional Brownian motion. As a consequence, the appropriately...