Some Ostrowski’s type inequalities for the Riemann-Stieltjes integral ${\int }_a^{b}f\left(e^{it}\right)du\left(t\right)$ of continuous complex valued integrands $f:𝒞\left(0,1\right)\to ℂ$ defined on the complex unit circle $𝒞\left(0,1\right)$ and various subclasses of integrators $u:\left[a,b\right]\subseteq \left[0,2\pi \right]\to ℂ$ of bounded variation are given. Natural applications for functions of unitary operators in Hilbert spaces are provided as well.